Landscape types and pH control organic matter mediated mobilization of Al, Fe, U and La in boreal catchments

Stephan Köhler1, Fredrik Lidman2, Hjalmar Laudon3
1 aquatic sciences and assessment, University of agricultural sciences
2 Dept. of Ecology and Environmental Science, Umeå University, SE-901 87 Umeå, Sweden
3 Dept. of Forest Ecology and Management, Swedish University of Agricultural Sciences, SE-901 83 Umeå, Sweden

O 8.8 in Trace element and metal biogeochemistry

14.07.2014, 16:15-16:35, H20

In this study we present data from a seven-year time series from 15 nested streams within a 68 km2 catchment, covering a pH gradient of almost three units. We demonstrate that the two landscape types, forest and wetlands, control the relative mobilization of Al and Fe in this boreal landscape. The La/U ratio is almost constant across the whole catchment despite large variations in pH, Al/Fe and TOC, whereas U and La mobilization increases with increasing contribution of deeper soils and groundwater further downstream.  High Al/TOC ratios in the forested catchments suggest that Al originates from the underlying mineral soils, and low Al/TOC ratios derive from wetlands where Al is retained. We observe a competition effect on the binding to TOC between Al and La and also that the relationship between TOC, Al and La changes from the smaller (0.05-2 km2) catchments to larger (3-68 km2) downstream locations. As pH increase downstream, Al and Fe are gradually removed from the aqueous phase by precipitation of particulate gibbsite-like phases and ferrihydrite. This selective removal of Al and Fe from TOC binding sites results in higher La, and U concentrations downstream. Observed element patterns (U, La) and the range of upper continental crust normalized (La/Nd)UCC and (La/Yb)UCC in the near stream, riparian zone were very similar to the observed ratios across the whole catchment. The rising  (La/Nd)UCC over (La/Yb)UCC may be due to a selective removal of REE binding to ferrihydrate in the riparian soil, the result of two distinctly different end-members but most probably not due to the in-stream precipitation of ferrihydrate or gibbsite-like phases.

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Letzte Änderung 04.04.2014